Public Comment - Exhibit A
From: Miranda Marti To: Commission-Public-Records; stacy@350seattle.org Subject: [EXTERNAL] Written public comment for the 10/26 Commission Meeting Date: Monday, October 25, 2021 2:50:55 PM Attachments: Maritime Solutions Team 10_26 Written Testimony.pdf WARNING: External email. Links or attachments may be unsafe. Good afternoon, I have attacheda pdf of the written public comment that the 350 Seattle Maritime Solutions team would like to submit for the October 26th Port Commission meeting. Please let me know if you have any questions or if you haveany difficulty accessing the attached document. Sincerely, Miranda Marti October 25, 2021 Re: Public Comment for the 10/26 Port of Seattle Commissioner Meeting Dear Port of Seattle Executive Director & Commissioners, The 350 Seattle Maritime Solutions team is providing the following written public comment regarding the accelerated climate targets and the first reading of the Maritime Clean Air Action Plan (MCAAP). We support the Executive Director adopting the recommended accelerated GHG targets & timelines AND also note the following regarding the MCAAP plans to meet these targets: 1. The Scope 3 emission reduction plans rely on advocacy for policies, regulations and technology that are not yet available. We support the Port of Seattle investing in advocacy, and also recognize that the port needs to consider alternate plans if advocacy and industry do not yield the necessary results to meet these targets. 2. Within the MCAAP Clean Air Action Plans' common accountability framework, we view the commitment to review and update implementation plans as critical to the credibility of the MCAAP. Accelerating targets and timelines is only meaningful if there is a realistic path to meet them. As a contingency if advocacy and technology do not yield the necessary outcomes to meet climate goals, we would also like to see alternate plans to: Reduce cruise calls to zero as quickly as possible until zero carbon cruise ships run under ethical business practices are available. Rethink business as usual. Given the Port of Seattle is one of the largest landholders in King County, it is reasonable that we expect new ideas for revenue in a green economy vs. business as usual accommodation of difficult to decarbonize transportation sectors & the fossil fuel industry. We expect to see the port demonstrate that these bold climate goals are achievable under the current state charter for economic growth. If they are not, we expect the Port of Seattle to work to align the state charter for port districts with climate realities & environmental justice. In solidarity with the Duwamish River Cleanup Coalition, we would like to amplify the demands and concerns that they have raised in written comments to the Port of Seattle and the Northwest Seaport Alliance, including that the Port of Seattle: Prioritize the health of the Duwamish Valley (DV) residents, taking actions to reduce GHG and air pollution for DV communities first Articulate the specific actions or steps the Port will take to "support" real time air monitoring. DRCC has been fighting for years for the port to conduct real time air monitoring at port sites and in the DV community, and for the port to pair diesel particulate matter reductions with a health indicator as part of their accountability plan. Expand and develop more areas for carbon sequestration in the DV and ensure that any plans for the purchase of carbon credits mentioned in the MCAAP benefit the DV. With regards to the final point above about carbon credits and offsets: we also stand by the objections to the use of carbon offsets that we raised in our April 8, 2021 comments to the Port of Seattle regarding the 2021 MCAAP Draft1. We do not support the use of carbon offsets to achieve climate goals. If the port does move forward with a plan for carbon offsets, however, we stand in solidarity with the Duwamish River Cleanup Coalition's demand that any such plan benefit Duwamish Valley communities. Thank you for your time and attention. If you would like to follow up with us regarding any of these comments, please reach out to Miranda Marti (mirandahmarti@gmail.com) or Stacy Oaks (stacy@350seattle.org). Sincerely, Miranda Marti and Stacy Oaks, co-leads 350 Seattle Maritime Solutions Team https://350seattle.org/solutions-port 1 OGV3 "Regarding the action to evaluate an optional carbon offset or "Good Traveler" type program for Seattle's homeport cruise passengers in coordination with cruise lines, our note on XS3 objecting to Cap & Trade programs on the grounds of environmental justice applies here as well. We advocate for the expansion of carbon sequestration areas, but not as a trade off for the climate and public health harms associated with cruise ship emissions." From: JOHN A BIRNEL To: Commission-Public-Records Subject: [EXTERNAL] Public testimony for Oct 26th Port meeting Date: Monday, October 25, 2021 6:23:20 PM WARNING: External email. Links or attachments may be unsafe. Thank you for the work you are doing in Scope 1 and 2 to reduce carbon pollution at the Port. Scope 3 emissions related to the Port are, of course, more complicated. I would urge you to "bit the bullet" and initiate a public campaign for the flying public, including business customers, to drastically reduce their flying. I believe this would be consistent with your mission to promote the common good, help in your efforts to realistically reduce Scope 3 emissions, and reduce the need for further airport expansion. If you seriously question whether your mission could encompass such a campaign, I would request that you advocate an appropriate broadening of the enabling RCW 53 law. John Birnel, a resident of Seattle and a volunteer of the Aviation Team of 350 Seattle, a group that works for climate justice. From: Robin Briggs To: Commission-Public-Records Subject: [EXTERNAL] Scope 3 emissions MIA in Port GHG Inventory Date: Tuesday, October 26, 2021 8:01:19 AM WARNING: External email. Links or attachments may be unsafe. I am writing to ask for improvements in how the Port of Seattle calculates its greenhouse gas emissions, specifically its scope 3 emissions. Scope 3 emissions for maritime counts only emissions within the immediate area only as far as Point No Point. The emissions should include half the round trip, so it should count either the trip from the home port to Seattle, or from Seattle back to the home port. Counting only what is emitted in the Sound ignores the bulk of the emissions. It's like sweeping it under the rug. The Scope 3 emissions for aviation are in a more dire strait -- "Coming Soon!" according to your website. It's been coming soon for quite awhile. Somehow King County managed to count the emissions from SeaTac Airport, why can't the Port of Seattle? If the Port wants to be a trusted entity, it needs to engage in an open, transparent process, and report the emissions, how the emissions were calculated, and what steps the Port can take to reduce them. I appreciate the work the Port has done to reduce its scope 1 and 2 emissions. The Port needs to step up to the plate and address the scope 3 emissions as well. I have grown children, and I am concerned about the climate not just for their sake, but for my own. Climate change is happening now, it is coming faster than anticipated, and the consequences are more severe. Please don't pretend the Port doesn't have scope 3 emissions. Report them, and then together as a community we can figure out what to do next. Thanks very much for your attention to this matter, and for your public service. Robin Briggs From: Elizabeth Burton To: Commission-Public-Records Subject: [EXTERNAL] Re: Public Comment Date: Tuesday, October 26, 2021 1:21:37 PM WARNING: External email. Links or attachments may be unsafe. Hello, Clerk, I was at the check-in to give public comment this morning, and waited from 11:30 until 1:16 pm to deliver my public comment at today's commission meeting. I pressed *6 multiple times when my name was called, but despite this, you apparently couldn't hear me. I am extremely disappointed that I could not deliver the comments during the meeting, due to technical problems beyond my control. Therefore, I am asking to submit my comments in written form. Thank you, Elizabeth Burton Good afternoon, Commissioners and Port Staff. My name is Elizabeth Burton. For the last year and a half, the Port's website, spokespeople, and commissioners have repeatedly claimed that the Port has met its climate goals ten years early. This claim is based on projects that reduce scope 1 & 2 emissions; it ignores entirely the fact that scope 3 emissions dwarf scopes 1 & 2, and that the Port is not at all on track to meet its scope 3 climate goals. Claiming that you've met your climate goals 10 years early, with no acknowledgement that there are larger, more significant climate goals you're not meeting, keeps both the media and the public in the dark about the magnitude of your runaway scope 3 emissions: it hides the harm that they do, and shields you from pressure to reduce them. It is also the opposite of transparency and accountability, two values that are enshrined in your Century Agenda. Going forward, I ask that you be more honest about your climate work, and refrain from this kind of misleading spin. I also ask that you take responsibility for the 90% of scope 3 emissions that you are currently ignoring: those emitted outside our airshed. A recent legal analysis of the Paris Agreement shows that, contrary to industry claims, there is no legal basis for excluding international shipping and aviation emissions from parties' obligation to reduce emissions. The analysis found that no state should discharge responsibility for monitoring or controlling international shipping or aviation emissions to the IMO or the ICAO. Under the Paris Agreement, emission reduction plans must be economy-wide, and must serve the central aim of the Agreement, which is to limit global temperature increase. Therefore, action must be taken on all emissions that affect climate. Thank you. On Oct 26, 2021, at 8:41 AM, Commission-Public-Recordswrote: Thank you Elizabeth Burton, Join us via yourmobile or laptop device on through Teams or call into the number provided below at11:30 a.m. PSTon Tuesday October 26, 2021 in order to be marked present and ready to speak. A member of port staff will join the call to take a roll call of the names we have listed and go over the procedure. Please plan to call from a location with as little background noise as possible. You should expect to be on the line for between 30-60 minutes as we dispose of preliminary business on the agenda and we hear from other public commenters. While it's not possible for us to predict how many people will comment on October 26, we expect individual comment time to be limited to two minutes and all rules of order and decorum will apply as usual. If you have any questions please let us know. We appreciate your dedication to public health and your interest in participating in the Port of Seattle Commission meeting. ______________________________________________________________________ __________ Microsoft Teams meeting Join on your computer or mobile app Click here to join the meeting Or call in (audio only) +1 425-660-9954,,737511203# United States, Seattle (833) 209-2690,,737511203# United States (Toll-free) Phone Conference ID:737 511 203# Find a local number|Reset PIN Learn More|Meeting options ______________________________________________________________________ __________ Best Regards, Commission Public Records From: Sharla Dodd To: Commission-Public-Records Subject: [EXTERNAL] Public Comment Port Meeting 10/26/21 Date: Monday, October 25, 2021 9:11:03 PM WARNING: External email. Links or attachments may be unsafe. Dear Port of Seattle Commissioners, I want to commend your acknowledgement of aviation's impact on climate change through the strengthening of the Port's emissions targets. Though the reduction of Scope 3 emissions is undoubtedly the biggest challenge, the Port's ambitious plans to reduce Scope 1 and 2 emissions are an important step in the right direction. Unfortunately your goal of Scope 3 carbon neutrality does nothing to require any emissions reductions and as such is inadequate. Carbon offset programs haven't proven to result in significant emissions reductions and are mostly located in the developing world which often leads to land grabbing and local conflict (not to mention lack of oversight and corruption, making a true accounting difficult). Using carbon neutrality as a goal only serves to allow the wealthy of the world to avoid personally reckoning with the environmental damage they cause while they greenwash away their guilt. Additionally, Sustainable Aviation Fuels (SAFs) are the not panacea that they are purported to be as they barely reduce CO2 per mile flown and (as you recognize) there is limited capacity for biofuel production. SAF production does not, at this time nor predicted in the near future, have the capacity to fulfill the rapidly growing thirst for aviation in any meaningful way. Rather than claiming that Scope 3 emissions are outside of your immediate control and waiting for technological advances in airplanes to materialize, the Port could instead take decisive action and lead our state and nation in the right direction in the fight to mitigateclimate change. The Port needs to acknowledge that flight reduction (the opposite of the anticipated doubling of flight demand within mere years) is what is required and the SAMP must be altered to reflect our current climate reality. I fear for our future if our liberal, environmentally-conscious city's leaders aren't able to take the necessary steps to stave off the ever-worsening consequences of climate collapse in a timely manner. Thank you for your time, Sharla Dodd, Seattle resident From: Alexa Fay To: Commission-Public-Records Subject: [EXTERNAL] Citations on Health Impacts of SAFs Date: Tuesday, October 26, 2021 6:04:25 PM Attachments: laiti aircraft soot conventional and biofuels 2019.pdf WARNING: External email. Links or attachments may be unsafe. Greetings, I wanted to follow up with Commissioner Felleman's request for citations on the health impacts of Sustainable Aviation Fuels (SAF). This article discusses health impacts of different fuels including kerosene and biofuels and can be foundhere. I'm highlighting the area on biofuels below: "Evidence of increased cell membrane damage and oxidative stress in the cell cultures was identified. Oxidative stress accelerates ageing of cells and can be a trigger for cancer or immune system diseases. The particles turned out to cause different degrees of damage depending on the turbine thrust level and type of fuel: the highest values were recorded for conventional fuel at ground idling, and for biofuel in climb mode. These results were surprising. The cell reactions in the tests with conventional kerosene fuel at full engine thrust - - comparable with takeoff and climb- in particular, were weaker than expected. "These results can be partly explained by the very small dimensions and the structure of these particles," says Anthi Liati, specialized in the nanostructure of combustion aerosols at Empa. Moreover, the cells responded to biofuel exposure by increasing the secretion of inflammatory cytokines, which play a central role in our immune system. "This reaction reduces the ability of airway epithelial cells to react appropriately to any subsequent viral or bacterial infections," explains Marianne Geiser." Another article which I have attached to the email discusses soot reactivity from traditional and biofuels from aircraft use. I've highlighted a key point from thepaper's conclusion below: "At climb-out conditions the HEFA blend soot shows higher reactivity thus potentially bearing higher health risk compared to Jet A-1 produced soot at this thrust level. However, HEFA blending produces lower soot amounts than Jet A-1 and this needs to be taken into account besides soot reactivity, in order to obtain the net effect" I'd be happy to share more on the health impacts of aviation and maritime emissions, as well as the economic benefits that would come from reducing emissions-related health disparities and issues. Thank you, Alexa Fay Environmental Pollution 247 (2019) 658e667 Contents lists available at ScienceDirect Environmental Pollution journal homepage: www.elsevier.com/locate/envpol Aircraft soot from conventional fuels and biofuels during ground idle and climb-out conditions: Electron microscopy and X-ray micro-spectroscopy* A. Liati a, *, D. Schreiber a, P.A. Alpert b, Y. Liao a, B.T. Brem c, P. Corral Arroyo b,J.Hua, H.R. Jonsdottir d, M. Ammann b, P. Dimopoulos Eggenschwiler a a Empa, Swiss Federal Laboratories for Materials Science and Technology, Automotive Powertrain Technologies Laboratory, CH-8600, Dbendorf, Switzerland b PSI, Paul Scherrer Institute, Laboratory of Environmental Chemistry, CH-5232, Villigen, Switzerland c Empa, Swiss Federal Laboratories for Materials Science and Technology, Laboratory for Advanced Analytical Technologies, CH-8600, Dbendorf, Switzerland d University of Bern, Institute of Anatomy, CH-3012, Bern, Switzerland a r t i c l e i n f o a b s t r a c t Article history: Aircraft soot has a signicant impact on global and local air pollution and is of particular concern for the Received 14 September 2018 population working at airports and living nearby. The morphology and chemistry of soot are related to its Received in revised form reactivity and depend mainly on engine operating conditions and fuel-type. We investigated the 17 January 2019 morphology (by transmission electron microscopy) and chemistry (by X-ray micro-spectroscopy) of soot Accepted 21 January 2019 from the exhaust of a CFM 56-7B26 turbofan engine, currently the most common engine in aviation eet, Available online 22 January 2019 operated in the test cell of SR Technics, Zurich airport. Standard kerosene (Jet A-1) and a biofuel blend (Jet A-1 with 32% HEFA) were used at ground idle and climb-out engine thrust, as these conditions highly Keywords: inuence air quality at airport areas. The results indicate that soot reactivity decreases from ground idle Aircraft emissions Soot to climb-out conditions for both fuel types. Nearly one third of the primary soot particles generated by TEM nanostructure the blended fuel at climb-out engine thrust bear an outer amorphous shell implying higher reactivity. HEFA This characteristic referring to soot reactivity needs to be taken into account when evaluating the Biofuel advantage of HEFA blending at high engine thrust. The soot type that is most prone to react with its surrounding is generated by Jet A-1 fuel at ground idle. Biofuel blending slightly lowers soot reactivity at ground idle but does the opposite at climb-out conditions. As far as soot reactivity is concerned, biofuels can prove benecial for airports where ground idle is a common situation; the benet of biofuels for climb-out conditions is uncertain. 2019 Elsevier Ltd. All rights reserved. 1. Introduction particulate matter (PM). Solid PM comprises mainly soot and to a small extent ash (metal particles). Soot generated by road transport Aviation affects global and local air quality, and inuences is known to have adverse effects on human health while studies climate, the environment and human health. Air trafc has a global concerning the health impacts of jet exhaust soot are limited (Touri annual growth of ~5% (Leahy, 2017) and is expected to rise in the et al., 2013). future thus increasing the environmental and human health con- Introduction of biofuels in road transport has proven successful cerns and posing new challenges for further research on aircraft for soot reduction (e.g. (Boot et al., 2009; Klein- emissions. Aircraft emissions include gaseous components such as DouwelDonkerbroek et al., 2009; Westbrook et al., 2006),). Bio- CO2, NOx, CO and SOx, volatile organic compounds, as well as solid fuels have been tested recently also in aviation in form of blends with standard aviation fuel. Note that aviation fuels contain only trace levels of oxygen (ASTM D7566-18, 2018) but the use of * This paper has been recommended for acceptance by Bernd Nowack. oxygenated biofuels in aviation is a topic of scientic discussion * Corresponding author. (Llamas et al., 2013). Common biofuels with bene cial E-mail address: anthi.liati@empa.ch (A. Liati). https://doi.org/10.1016/j.envpol.2019.01.078 0269-7491/ 2019 Elsevier Ltd. All rights reserved. A. Liati et al. / Environmental Pollution 247 (2019) 658e667 659 environmental potential are hydro-processed esters and fatty acids The same conclusion was reached in a more general study on (HEFA), as well as those produced by a Fischer-Tropsch synthesis aircraft PM emissions including TEM characterization (LiatiBrem (FT) (Rojo et al., 2015). The few studies dealing with aircraft engine et al., 2014). In addition, Vander Wal et al. (Vander Wal et al., exhaust characterization with biofuel blends (Rojo et al., 2015; 2014) reported signicant oxygen content on soot surfaces which Beyersdorf et al., 2014; Timko et al., 2010) conclude that biofuel may inuence the hydrophilic properties of soot. blending reduces soot emissions. Regarding biofuel use in road transport, soot morphology shows A key issue that can elucidate the impact of soot on health and a lower degree of structural order, and thus higher reactivity, than the environment is the knowledge of physical and chemical prop- diesel soot (Lapuerta et al., 2012; Song et al., 2006; Yehliu et al., erties in the micro- and nano-scale. Physical properties refer to the 2011; Liati et al., 2012; Vander Wal and Tomasek, 2003). To our morphology of soot particles (size and internal nano-structure, i.e. knowledge, TEM studies on soot from alternative fuels in aviation degree of atomic order). These properties vary depending on type are lacking. of the fuel used and the engine operating conditions, i.e. the fuel/air The chemical composition of soot can also provide important ratio during combustion, as well as ame temperature and resi- information on the degree of reactivity. Carbonyl or carboxyl dence time of the particles in the ame (Timko et al., 2010; Braun, groups, for instance, can increase soot reactivity with respect to 2005; Kinsey et al., 2011; Lobo et al., 2012; Petzold et al., 1999; pure carbon since the energy needed to remove oxygen is lower Vander Wal et al., 2014). Soot morphology and chemistry reect its than the one needed to remove elemental carbon. A previous study reactivity, important for determining the oxidation capacity of soot reported that surface bound carboxyl functional groups tend to and/or its capacity to react with the surrounding, in general. The decarboxylate in the presence of ozone, sunlight and adsorbed formation of ice clouds from soot has also been related to soot water (Smith and Chughtai, 1995). Soot in the ambient atmosphere morphology and chemical composition (KulkarniChina et al., 2016; has been extensively characterized using scanning transmission X- Knopf et al., 2018). Moreover, the hydrophilic character of soot, in ray microscopy coupled to near edge X-Ray absorption ne struccombination with the active particle number (particles serving as ture (STXM/NEXAFS) spectroscopy (Liati et al., 2013; Moffet et al., condensation nuclei versus total particles) are properties used in 2016; TakahamaGilardoni et al., 2007). STXM/NEXAFS yields X- recent models on contrail and cirrus formation (Hendricks et al., ray absorption peaks at particular X-ray energies quantifying the 2011). molecular bonding environment of carbon atoms. Ground based A series of studies have been devoted to the oxidation reactivity particle sampling shows that soot is typically found at the center of of soot in road transport and showed that soot with small particle particles mixed with organic and inorganic matter as its atmosize (large surface to volume ratio) and amorphous internal nano- spheric residence time increases (Moffet et al., 2016; structure (low thermodynamic stability) favor oxidation reac- TakahamaGilardoni et al., 2007). To date, only a single study using tivity, in contrast to large particle sizes and well-ordered nano- NEXAFS (in electron yield mode, as opposed to transmission mode structures (e.g. (Pahalagedara et al., 2012; Yehliu et al., 2012)). in STXM) spectroscopy on soot from an aircraft engine using con- Whether the size weighs more than the internal nano-structure in ventional fuel is available and revealed that soot surfaces can be determining the degree of soot reactivity is unclear but there are more oxidized than the soot core, on average (Parent et al., 2016). indications that the size is rather the more important parameter Within the framework of the present paper, the morphology (by (Lapuerta et al., 2012). Regarding the chemical composition of soot TEM) and chemistry (by NEXAFS spectroscopy) of soot generated by versus oxidation reactivity, different studies (Lamharess et al., 2011; a CFM 56-7B26 turbofan engine, currently the most common en- Song et al., 2006; Yehliu et al., 2011) arrive at different conclusions gine in aviation eet, operated with standard aviation conventional but show a trend for high reactivity when soot has high oxygen kerosene (Jet A-1) and an alternative fuel (HEFA) blend at ground content. Although not adequately researched and established, soot idle and climb-out conditions were investigated. These engine reactivity can be considered, in a more general sense, as referring to thrust conditions were chosen as they are crucial for the population the availability of atoms on the particle surface and bulk for reac- working at airports and leaving in the surrounding. The turbofan tion, not strictly with oxygen only. engine was operated in the test cell of SR Technics, Zurich airport. Soot particles resulting from different fuel types, engine oper- The aim of the paper was to investigate and inter-compare the ating conditions and/or ambient temperatures have comparable morphological and chemical characteristics of soot generated by but not identical morphologies. The primary particle constituents the different fuel types and thrust levels, evaluate soot reactivity for of the agglomerates all share a nearly spherical shape and consist of each condition and examine the environmental benets from the generally concentric, carbon-dominated layers (approaching the use of alternative fuels from the soot reactivity point of view. graphene structure) of variable length, separation distances and periodicity. The nano-structure of soot is well demonstrated on 2. Experimental high resolution transmission electron microscopy (HRTEM) images. With increasing degree of structural order, carbon lamellae length 2.1. Sampling setup and procedures increases (less edge atoms are exposed), separation distances between carbon lamellae decreases and reactivity is reduced. In The experiments were carried out in the engine test cell of SR addition to the primary particle morphology, the morphological Technics at Zurich airport, within the framework of the project characteristics of soot agglomerates may also inuence reactivity. EMPAIREX. An in-service CFM 56-7B26 hi-bypass turbofan engine While numerous studies use TEM to determine morphological was used, popular in the current aircraft eet and used on the characteristics of soot generated in road-trafc, only few publica- Boeing 737 short-to medium-range twinjet narrow-body airliner. tions are available on aircraft soot morphology. Popovicheva et al. This particular engine had 15'200 ight cycles (32'000 h wing time) (Popovitcheva et al., 2000) studied nano-structural parameters of and a stable performance during the entire campaign. The engine soot and report signicant water adsorption on soot generated by a thrust levels were controlled according to the engine combustor typical aircraft engine compared to non-polar gases. Detailed TEM inlet temperature (T3, proprietary value) for which the correcharacterization of aircraft soot was presented by (Vander Wal sponding thrust levels are known for standard atmospheric con- et al., 2014) and (Parent et al., 2016) reporting a clear variation in ditions (15 C, 1013.25 hPa). Idling thrust is affected by ambient the degree of soot crystallinity with engine thrust level, the lower conditions. In this work it corresponded to 3e4% of the maximum thrust soot exhibiting a lower structural order than at high thrust. sea level thrust output. During the experiments two different fuel 660 A. Liati et al. / Environmental Pollution 247 (2019) 658e667 types were used: i) Jet A-1 and ii) a blend consisting of Jet A-1 with spaced energy steps were taken and processed with publically 32% HEFA (Supplementary Table S2). HEFA fuel has many of the available software for automated X-ray image analysis (Moffet et al., properties of petroleum derived jet fuels the main difference from 2010). Spectra reported here were background subtracted by the Jet A-1 being the lower total aromatics and the sulfur contents OD at the carbon pre-edge (278e280 eV) and normalized to the (18.1% v/v and 490 ppm for Jet A-1, respectively and 11.3% v/v and spectral area at the carbon post-edge (305e320 eV) (Takahama 350 ppm for the HEFA- Jet A-1 blend, respectively). et al., 2010). PM was collected during climb-out (~85% engine thrust; P85) and ground idle conditions, directly on TEM grids (for soot 3. TEM results morphology) and on silicon nitride (Si3N4) membranes (for NEXAFS analyses). For each engine thrust condition, both Jet A-1 and HEFA 3.1. Size of agglomerates and primary particles blend were used. An additional experiment applying Jet-A1 fuel doped with 4% HEFA at nearly 100% thrust conditions ('Maximum The size of soot agglomerates and their primary particle con- Continuous') was conducted and used in STXM/NEXAFS analysis. stituents was determined from TEM images using the measuring Supplementary Table S1 summarizes the conditions during sam- tool of the software 'Digital Micrograph'.Thesizeoftheagglompling , including online measurements. Details on the sampling erates is taken here as their maximum length, that of the nearly setup and procedure and a schematic of the sampling equipment spherical primary particles by the diameter of their circular proare given in the supplementary information (section S1). jection. For the measurements we took into consideration isolated , freestanding agglomerates. Thus the agglomerate size 2.2. Transmission electron microscopy e image processing expressed as maximum length would be a representative and consistent gure allowing comparison between different thrust TEM studies were performed with a JEOL 2200FS TEM/STEM conditions. We have no indication for agglomeration on the TEM microscope equipped with an Omega lter, a Schottky eld emis- grid during sampling. The geometric mean diameters of the agsion gun at 200 kV, and a point to point resolution of 0.23 nm glomerates, as obtained by simultaneous online measurements (Electron Microscopy Center of Empa). The TEM instrument is are also listed in Supplementary Table S1. equipped with an EDX detector (JEOL EDX detector: EX-24065JGT) Based on 300e400 measurements, ground idle conditions result for elemental analysis. Images were taken in bright eld (BF) and in signicantly smaller agglomerates than climb-out. We deterdark eld (DF) STEM mode, as well as in TEM and HRTEM mode. For mined a modal size range of soot agglomerates and primary partioptimum contrast and distinction of nano-structural features, cles. For both Jet A-1 and HEFA blend fuel types, ~80% of soot particles located in holes of the carbon lm were chosen. agglomerates generated at ground idle conditions fall within the size Image processing of ve representative soot particles per thrust mode <40 nm (Fig. 1a). At 85% engine load, a modal size of condition and fuel type was carried out in order to quantify and 40e80 nm was observed accounting for ~35% of the particles, while compare the fringe length. For the quantication of the fringe another ~20% were between 80 and 120 nm. Inside the smallest size length we used MATLAB following a procedure suggested in range (<40 nm), idle Jet A-1 agglomerates are considerably smaller different recent papers (e.g. (Song et al., 2006; La Rocca et al., 2015)) than idle HEFA blend ones (Fig. 1b; Jet A1: ~45% are <20 nm versus including the following steps: image cropping, negative trans- HEFA blend: only ~15% are <20 nm). The increasing trend from low formation, image histogram equalization, Gaussian low-pass lter; to high thrust level identied for agglomerates is also observed for top hat transformation, binarization and skeletonization. Removal the primary soot particles (Fig. 1c): the big majority (~75e85%) at of artifacts (branch points removal) was most efcient by marking ground idle conditions for both fuel types was between 5 and 10 nm; the fringes by hand onto the HRTEM image of the soot particles. The at P85 the maximum (~30%) lies between 15 and 20 nm; ~60% of binary image was processed using MATLAB by applying the built-in them are 10e25 nm in diameter (Fig. 1c). HEFA blend at idle condiskeletonization function. The analysis was then automated and tions produces the highest percentage of the smallest primary parstandardized. ticles (~20% are 3e5 nm large in contrast to 2% of the Jet A-1 ones). The TEM images of Fig. 2 depict a representative view of the size 2.3. X-ray micro-spectroscopy (NEXAFS) and relative amount of soot agglomerates under P85 and ground idle conditions. The described differences between low and high Carbon functionalities in single particles were investigated with thrust conditions were also found in a previous TEM study of STXM/NEXAFS. A detailed overview of this technique can be found aircraft soot emissions (LiatiBrem et al., 2014), where ~60% of the in (RaabeTzvetkov et al., 2008). Focused single energy X-rays irra- primary particle sizes during taxiing (~7% thrust) were 10e15 nm diated particles deposited either on silicon nitride, Si3N4, mem- (mode 13 nm) and ~60% of primary particles under full thrust branes or TEM grids as sample substrates. Substrates were (~100% thrust) were 10e25 nm (mode 24 nm). Moreover, the retransported under a N2 atmosphere to the PolLux beamline sults of simultaneous online measurements of the size of soot ag- (X07DA) of the Swiss Light Source at the Paul Scherrer Institute. glomerates show the same trend as the TEM results STXM/NEXAFS analysis was conducted on a total of 44 particles and (Supplementary Table S1). Taking into account only the size of soot classied as either soot (10 particles), mixtures of organic and soot agglomerates and primary particles, i.e. not considering internal (13 particles) or organic only (21 particles). Scanning X-ray energies nanostructures and internal arrangement of primary particles were 278e320 eV; absorption was measured with a high spatial within the agglomerate, our results indicate higher reactivity for resolution of 35 35 nm to observe carbon bonding. This energy ground idle particles of both fuel types compared to P85 particles. It range covers electron binding energies for ground state electron is reminded that small primary soot particles and small agglomorbitals of the carbon atom (carbon K-edge). Absorption spectra erates tend to be more reactive than large ones (see earlier, were converted to optical density (OD) over the 2-D projected Introduction). particle area as a function of X-ray energy where OD ln(I/I0), and I and I0 are the transmitted and initial X-ray light intensities, 3.2. Internal nano-structure of primary soot particles respectively. Energy calibration was performed by comparing the measured lowest energy peak of polystyrene with its literature Primary soot particles from both investigated fuel types and value (Dhez et al., 2003). Series of particle OD images at closely engine thrust conditions consist of discontinuous carbon lamellae A. Liati et al. / Environmental Pollution 247 (2019) 658e667 661 (fringes) (Fig. 3). Discontinuities in carbon lamellae are marked by are observed either inside the particle or attached on it. It is recalled grey areas on the images where no fringes can be distinguished and that ash (or metal PM), represents the non-carbonaceous inorganic correspond to regions of highly disordered arrangements, likely fraction of solid PM at the aircraft exhaust originating mainly from due to irregular and episodic incorporation of organic compounds lubricating oil and to a small degree from fuel additives. Depending during particle growth. on the saturation level, ash may occur as separate particles attached Representative HRTEM images are given in Fig. 3. Amorphous onto soot or inside soot particles. Ash may also include fragments cores usually constitute a very small part of the particle volume; detached from various engine components (engine wear). particles with strongly bent carbon lamellae are observed almost to the particle's center. Abundance of curved lamellae at particle in- 3.2.1. Carbon lamellae (fringe) length - image processing teriors indicates a relatively high functionality and therefore high HRTEM images of primary soot particles qualitatively reveal that reactivity of soot at this stage of particle development. More or less ground idle particles (Fig. 3A) have a lower degree of order with planar, slightly deformed lamellae of various length form packages respect to carbon lamella length and arrangement than the P85 of different thickness and orientation overlying the particle interior particles (Fig. 3B). Carbon lamella length is the continuous linear and resulting in an approximately concentric arrangement. distance of an atomic carbon layer plane uninterrupted by any A peculiarity in soot nanostructure is identied for the P85 soot amorphous interference. of the HEFA blend: a considerable part of the examined particles Fig. 4 shows histograms of fringe length frequency. It is note- show a highly disordered, nearly amorphous outer shell 2e8nm worthy that each individual soot particle used for the quantication thick (Fig. 3C). We estimate the percentage of the particles bearing of the fringe length gave consistent results for each thrust condition this type of amorphous shell to about 30e40% of the totally and fuel type examined. Data is presented for the same engine observed particles. Note that this observation requires high reso- thrust with different fuel types (Fig. 4a and b), and again for the lution imaging which cannot go along with solid statistics. Thus the same fuel type and different engine thrust (Fig. 4c and d). It is noted 30e40% estimation is only a rough approximation. Note also that that Fig. 4e comparing P85 soot particles with and without the no expansion and, in general, no deformation of this amorphous outer amorphous shell was determined by excluding the amorshell was observed under the electron beam. The outer shell phous shell. The results indicate that soot particles with the described above has been identied also in P85 soot generated with shortest graphene lamellae, which are the most reactive, are pro- HEFA-doped fuel (4% HEFA), but was not observed in soot produced duced by Jet A-1 fuel at ground idle conditions (Fig. 4a). The second with Jet A-1. An amorphous outer shell has been reported by La most reactive particle type in terms of graphene length is idle soot Roca et al. (La Rocca et al., 2015) for primary particles of soot from generated by HEFA blend. The least reactive soot, i.e. the one with engine oil of a modern direct injection gasoline engine. In our case, the highest amount of long graphene lamellae is the one produced an origin of this soot type from engine oil cannot be completely by HEFA blend at P85 conditions. However, taking into account that excluded but the fact that it has been found only when using HEFA around 30e40% of P85 HEFA blend soot particles are enveloped by a fuel and only at high thrust conditions favors its formation in ~2e8 nm thick amorphous (highly reactive) shell (Fig. 3C), it is connection with the use of HEFA fuel type. Finally, in a few P85 soot quite likely that P85 HEFA blend soot is overall more reactive than particles produced by both Jet A-1 fuel and HEFA blend ash particles P85 Jet A-1- soot. Moreover, the P85 HEFA blend particles with an Fig.1. Size distribution of soot agglomerates (a, b) and primary particles (c) for ground idle and P85 thrust conditions with Jet A-1 and HEFA blend showing signicantly lower sizes for idle conditions. 662 A. Liati et al. / Environmental Pollution 247 (2019) 658e667 Fig. 2. TEM images demonstrating the higher abundance and larger agglomerate sizes of P85 (left panel) versus ground idle conditions (right panel). The P85 image was taken with a100000 magnication, the ground idle one with 200000x to make particles distinguishable. The images are representative for both fuel types. Fig. 3. HRTEM images of soot particles depicting their internal nanostructure. (A) ground idle conditions; (B): P85 thrust; (C) P85 thrust with HEFA blend showing an amorphous external shell (greyish) around the carbon lamellae-bearing part. Black squares in (A) and (B) mark examples of crystallites: Images (A and B) are representative for both fuel types. outer amorphous shell have more abundant short fringes in the shows d002 for HEFA blend soot with and without the amorphous inner (non-amorphous) part than the particles without this shell. shell (section 3.2; Fig. 3C). The particles with the highest d002 Finally, differences in fringe length distribution between the two percentage deviating most from that of graphite (0.335 nm), i.e. the fuel types are less pronounced for ground idle particles. most reactive ones, are those generated at ground idle conditions using Jet A-1 fuel. At P85 (Fig. 5b), the HEFA blend soot produced particles with d002 closer to that of graphite compared to Jet A-1 3.2.2. Separation distances (d002) and periodicity of carbon fuel. In general, both fuel types at P85 thrust produce soot with d002 lamellae closer to graphite than at ground idle. This difference is more The separation distance between adjacent carbon lamellae, d002 pronounced for the HEFA blend (compare Fig. 5c and d). The HEFA is equivalent to the distance between individual graphene planes in blend P85 soot particles show comparable d002 distribution patthe crystal lattice of graphite. As a result of randomly folded carbon terns irrespective of the presence of an outermost amorphous shell lamellae slipped out of alignment, known as turbostratic stacking, (Fig. 5e). In Fig. 5f, the mean d002 values (with the standard deviirregular separation distances are common in soot particles, also in ation), as well as the median values have been plotted, indicating a the examined ones. The carbon lamellae pattern of soot particles tendency of increasing crystallinity (decreasing d002) from ground imaged on the HRTEM images is an interference pattern between idle to P85 conditions for both fuel-types, as well as from Jet A-1 non-diffracted and diffracted electrons in the beam and is depicted soot to HEFA blend soot. As for the periodicity, maximum values of in form of different degrees of brightness. For a quantication of the 4 and 5 were measured for idle and P85 soot, respectively, for both separation distances between carbon lamellae, the prole line plot fuel types. The width and amount of the crystallites is higher for of Digital Micrograph was applied. This tool can depict variations of P85 soot than for idle one, for both fuels. the brightness across successive carbon lamellae and can be Conclusively, d002 values and periodicity indicate a trend of transformed to numerical data thus providing the spacing between increasing crystallinity from ground idle to 85% engine thrust and dark and bright fringes, as well as the periodicity. Various elds of from Jet A-1 fuel to HEFA blend. The presence of an amorphous rim view were selected on HRTEM images where adjacent carbon in HEFA blend P85 particles may, however, inverse this trend for the lamellae were nearly straight and formed crystallites (see earlier, P85 conditions, possibly rendering the HEFA blend P85 soot overall section 3.2). d002 was measured from totally 155 to 180 carbon more reactive than the Jet A-1 P85 one. Table 1 summarizes the lamellae per particle type. morphological features of soot for the different engine thrust levels Fig. 5 presents histograms of d002 comparing the different fuel and fuel types. types (Fig. 5a and b) and engine thrust levels (Fig. 5c and d). Panel e) A. Liati et al. / Environmental Pollution 247 (2019) 658e667 663 Fig. 4. Distribution of graphene sheet length of primary soot particles generated under idle and P85 engine thrust with Jet A-1 and HEFA blend fuel types. Bin size is 0.3 nm. AR: amorphous rim. 3.3. X-ray micro-spectroscopy (NEXAFS) exception at 286.0 eV seen for ~100% engine load with 4% HEFA- doped fuel, indicating phenolic (C-OH) bonding (MoffetTivanski NEXAFS spectroscopy was applied on a series of samples and Gilles, 2011). We do not report on precise proportions of par- collected under the following engine thrust and fuel types: (i) ticles that are either soot or organic-type using NEXAFS, as this ground idle with Jet A-1, (ii) 85% with Jet A-1, (iii) 85% with Jet A-1/ would require investigation of a very large amount of particles and 32% HEFA blend and (iv) ~100% engine thrust with 4% HEFA doped is beyond the scope of our work. The exact organic-type could not Jet A-1 fuel. be clearly identied using STXM/NEXAFS. Some theoretical possi- Fig. 6 shows average NEXAFS spectra of analyzed material. Those bilities include deposited particles of engine lubrication oil or which are ascribed exclusively to soot are shown in Fig. 6a and have particles nucleated from semi-volatile organics in the exhaust as it a characteristic X-ray absorption peak at about 285.4 eV corre- cools after leaving the engine or condensation of organic vapor to sponding to carbon-carbon double bonding with a similar OD buildup organic matter on the substrate during impaction. Howcompared with the carbon post-edge between 305 and 320 eV ever, we do not consider these possibilities as likely because we (MoffetTivanski and Gilles, 2011). These spectra were additionally never observed spherical shaped particles (droplets) indicative of identied as soot, based on the observed OD at 288.6 eV being less condensation on a substrate. Furthermore, the sampling strategy than or equal to the peak at 285.4 eV. The peak position and height (heating and prompt dilution) minimizes the potential for hofound in the analyzed spectra are qualitatively in agreement with mogenous nucleation. It is also unlikely, that the signal is from previous literature (Braun, 2005; Parent et al., 2016; Moffet et al., uniform condensation of organic matter because NEXAFS spectra 2010). Parent et al. (2016) investigated soot generated from an are normalized to the substrate signal exactly adjacent to particles. aircraft engine operating with common kerosene fuel at 85% load Organic matter with a characteristic peak at 288.6 eV has been using electron yield NEXAFS spectroscopy (black dashed line in observed to be always associated with ambient soot (Moffet et al., Fig. 6a). The spectrum from bulk primary soot particles is similar to 2016; Moffet et al., 2010; MoffetTivanski and Gilles, 2011; the ones obtained here for HEFA blend soot and for soot doped with Takahama and Russell, 2010; Moffet et al., 2013; Takahama et al., 4% HEFA at high thrust and shown as the red and green lines, 2007). Diesel soot (Braun, 2005) also has both carbon-carbon respectively. Similar spectra of soot in atmospheric samples double bonding and organic matter, however, peak positions depicting carbon-carbon double bonding peak position (285.4 eV) differ slightly from ours and other previous literature. are reported by (Moffet et al., 2010). Braun et al. (2006) investigated how X-ray exposure can In addition to soot, organic matter was also found on some of chemically transform or damage organic matter associated with the analyzed particles from all run conditions and fuel-types indi- diesel soot and observed that increasing X-ray exposure would cated by a peak at 288.6 eV corresponding to the carboxyl func- decrease absorption at 288.6 eV while increasing absorption at tionality (Fig. 6b(Moffet et al., 2010). We suggest that this organic 290.2 eV attributable to CO3 production. We did investigate damage matter is mixed with soot, as both 285.4 (carbon-carbon double due to X-ray exposure of the samples collected at 85% load with a bonding) and 288.6 eV peaks are always observed together. Most 32% HEFA blend and found that even doubling the X-ray dose does peak positions for organic matter are found at 288.6 eV with one not alter X-ray absorption spectra (Supplementary Fig. S3). 664 A. Liati et al. / Environmental Pollution 247 (2019) 658e667 Fig. 5. (aee): distribution of separation distances d002 between carbon lamellae measured from crystallites of primary soot particles generated at ground idle and P85 engine thrust with Jet A-1 and HEFA blend fuel types. Bin size is 0.025 nm; (f) mean/median d002 values vs. thrust level/fuel type exhibiting decrease of crystallinity from ground idle to P85 and from Jet-A1 to HEFA blend. AR: amorphous rim. Table 1 Summary of morphological characteristics of soot. Ground idle P85 P100 Jet A-1 HEFA blend Jet A-1 HEFA blend 4% HEFA doping Agglomerate size (nm) 9-40 (80%) 10-40 (80%) 40-80 (35%) 40-80 (35%) e 80-120 (20%) 80-120 (20%) Primary particle size (nm) 5-10 (75e85%) 5-10 (75e85%) 10-25 (60%) 10-25 (60%) e Fringe length (nm) 0.7e1 (~45%) 0.7e1 (~40%) 0.7e1 (~35%) 0.7e1 (~20%) e Inter-fringe distance d002 mean std dev./median 0.387 0.033/0.394 0.373 0.028/0.375 0.380 0.033/0.376 0.364 0.022/0.362 e Periodicity (max) 4 4 5 5 e Degree of graphitization (based on NEXAFS) 0.62 e e 0.76 0.71 Furthermore, all spectra did not have clearly discernable peaks at identied using existing methods. 290.2 eV with the exception of a single particle from samples The degree of graphitization in soot particles is an indicator of collected at ~100% engine load doped with 4% HEFA fuel soot reactivity, i.e. the more graphite-like particles tend to have less (Supplementary Fig. S2). Therefore, we claim the vast majority of reactivity (e.g. (Pahalagedara et al., 2012; Yehliu et al., 2012)). In particles may not have been susceptible to the beam damage as terms of NEXAFS related observables, the degree of graphitization observed by Braun et al. implying a different organic composition in carbonaceous material can be dened as the ratio, r ODCC/ despite a qualitatively similar spectral appearance. Finally, we ODCedge, where ODCC and ODCedge is the pre-edge subtracted OD at investigated oxygen NEXAFS spectroscopy on organic matter from the carbon-carbon double bonding peak (285.3 eV) and the C-edge the same sample and found similar spectra compared to organic step at 292 eV (Liati et al., 2013; di Stasio and Braun, 2006; Jager matter associated with soot from Moffet et al. (MoffetTivanski and et al., 1999). Compared to graphite in which r 1.55 (di Stasio Gilles, 2011)(Supplementary Fig. S2). We note that quantication of and Braun, 2006), our soot samples (Fig. 6a) have r 0.76, 0.71 soot in atmospheric aerosol particles and how they are mixed with and 0.62 when the engine was operated with 85% load and HEFA organic and inorganic material has proved highly useful, especially blend, ~100% load and 4% HEFA-doped Jet A-1 fuel and ground idle for predictions of direct radiative effects (Moffet et al., 2016; Fierce with Jet A-1 fuel, respectively (Table 1). We note that (Parent et al., et al., 2016). We conclude that those particles emitted from aircraft 2016) using 85% load and conventional fuel had r 0.74. This im- engine run on both conventional and alternative fuels can be plies that the HEFA blend used in our study at climb-out conditions A. Liati et al. / Environmental Pollution 247 (2019) 658e667 665 Fig. 6. NEXAFS spectra of soot (a) and soot with organic matter (b) on substrates for particles collected under different engine thrust conditions and fuel combinations. Spectra from previous studies on soot and associated organic matter (if present) are shown vertically shifted downwards for clarity for 85% engine thrust with unblended fuel (black) (Parent et al., 2016), ambient soot particles (dark grey) (Moffet et al., 2010) and diesel exhaust (light grey) (Braun et al., 2006). The black horizontal lines above the spectra mark energy ranges from 284.9 to 285.5eV, 286.7e287.3 eV, 287.0e288.5 eV, 288.3e290.0 eV and 290.0e290.7 eV corresponding to functionalities R(CC)R, R(C-OH), R(CO)R, R(CO)OH and CO3, respectively. has almost no impact on the degree of graphitization expressed in Vander Wal et al. (Vander Wal et al., 2014) suggest that the change the NEXAFS spectra. It is important to note the spatial scale of the in soot nanostructure from idle (more disordered) to P85 (better STXM/NEXAFS technique is not capable of resolving amorphous ordered) is driven by changing species contributing to soot surface carbon layers at soot surfaces with a thickness of a few nanometers, growth (PAHs, likely fuel-borne at low temperature and acetylene as seen on the HRTEM images (Fig. 3). Thus, we cannot claim this at higher temperatures). amorphous rim was not an organic carbon coating on the surface of A trend towards increasing degree of soot crystallinity was primary soot particles. observed in the present study for ground idle conditions when Jet A-1 was blended with HEFA fuel. At 85% thrust, the situation be- 4. Discussion comes more complicated due to the presence of a disordered 2e8 nm broad outermost particle shell in a considerable part of The smaller size of ground idle soot agglomerates and primary soot particles studied. The fraction of P85 HEFA blend soot without particles compared to that of P85 soot, for both fuel types investi- the amorphous outermost shell shows a slightly more graphitized gated implies that ground idle soot is the more reactive one in this nanostructure than P85 Jet A-1 soot. Moreover, the inner (crystalrespect. The smaller size of ground idle primary particles can be line) part of the P85 HEFA blend particles with the amorphous shell attributed to soot inception and oxidation mechanisms in the en- have shorter fringe length (indicating lower crystallinity) but gine combustor, which depend on air to fuel ratio, temperature and slightly lower inter-fringe distances (indicating higher crystallinity) residence time. However, the exact formation mechanisms of soot than the HEFA blend soot particles without this shell. It cannot be are highly complex and it is hard to distinguish which parameter(s) judged which of the above opposing characteristics (fringe length are responsible for the observed differences. More research is or inter-fringe distance) weighs more for ascribing a net result on needed to clarify these issues. the degree of crystallinity. The lower degree of crystallinity of ground idle soot compared The experiments of the present study indicate that the addition to P85 soot implies also higher reactivity and indicates that idle of HEFA favors the formation of slightly more graphitized soot. In particles are richer in organic carbon relative to elemental carbon. this case, temperature can be considered as an inuencing factor This inference is in line with the ndings of (Wey et al., 2007) and promoting graphitization of HEFA blend soot, as there are in- (Timko et al., 2010), who reported that the elemental carbon to dications that the addition of purely aliphatic species, such as HEFA organic carbon ratio increases with engine thrust level. An increase fuel, increases slightly the local ame temperature in the rich in the degree of crystallinity of soot with engine power is reported section of the combustor. The pure HEFA component used in this also by (Vander Wal et al., 2014), in a TEM study of soot generated study had a slightly higher specic energy content of 44.2 MJ/kg by a CFM-56-3 engine aboard a DC-8 aircraft fueled by a kerosene versus Jet A-1 used which had 43.3 MJ/kg). However, considering fuel type JP-8. On the other hand, Parent et al. (2016), who studied the partial and relatively extended (30e40%) presence of soot with the nanostructure of soot produced by a different engine (PowerJet, a nearly amorphous shell when using P85 HEFA blended (and 4% SaM146-1S17) burning Jet A-1 fuel and operated on a test facility HEFA-doped) Jet A-1 fuel, the soot generated with HEFA (blending (SNECMA, Villaroche, France) found no signicant variations in soot and doping) at high thrust is overall less crystalline, i.e. more nanostructure with engine operating regimes. The above authors reactive than the Jet A-1 one. Moore et al. (2017) investigated HEFA comment that different engines and fuels complicate a direct blended Jet A-1 fuel (50/50) at in-ight cruise conditions and comparison of soot generated under similar engine operating re- mention that the greatest effect of the HEFA blend on emissions is gimes and that the engine technology probably inuences the associated with a reduction in black-carbon-equivalent mass. The combustion conditions and the soot characteristics. nding of these authors is in line with the overall less crystalline As already mentioned in the Introduction, one parameter that P85 HEFA blend soot particles identied in the present study. The can inuence the degree of crystallinity is temperature. Tempera- crystalline part of the soot particles generated by burning HEFA ture which favors graphitization (de-hydrogenation) increases with blend can be ascribed to dehydrogenation (graphitization) and reengine thrust level. This would explain our results as to why the actions related to fuel pyrolysis (mainly production of C2H2 species) P85 soot is more crystalline than the idle one. In this respect, of Jet A-1 components of the blend, possibly promoted by HEFA- 666 A. Liati et al. / Environmental Pollution 247 (2019) 658e667 induced higher temperatures. As a result, CC chains are formed From the environmental point of view, the apparent nanoleading to a graphitized structure of soot particles. The amorphous structural defects of the ground idle soot, as well as the ones of shell of soot particles could potentially be attributed to an insuf- the P85 soot from HEFA blend (or HEFA-doped Jet A-1) with the cient quenching and oxidation of soot precursors within the outermost amorphous shell imply the presence of numerous combustor which is probably favored for the HEFA blend. Further reactive sites at the soot surface, such as unsaturated organics or research is needed to understand the precise mechanism (or hydroxyl groups, for instance. Indeed, oxygenated functional mechanisms) involved in the formation of such an amorphous shell groups were always observed on all samples from STXM/NEXAFS at the outermost part of soot particles. analysis. These oxygenated groups have a variety of functional As stated in the Introduction, studies on soot reactivity refer forms due to the various carbon K-edge absorption peaks (Fig. 6b). strictly to its oxidation capacity. However, it is plausible to hy- We also note that identied soot spectra in Fig. 6a further suggest pothesize that soot reactivity cannot be limited to its capacity for reactive sites due to the observed oxygenated groups. Of course, the oxidation only, but refers generally to the presence of atoms on the common and main feature in soot spectra is the CC peak which particle surface and bulk available for reaction. Such reactions may occurs at a consistent X-ray energy (285.3 eV) in agreement with occur when soot comes into contact with its surrounding, i.e. at- previous studies (Parent et al., 2016; MoffetTivanski and Gilles, mospheric components or cells. Aircraft soot emissions generated 2011). These soot types with numerous defected sites may have a at ground level (ground idle) and close to ground level (climb out) different behavior towards atmospheric components compared to contribute to an increase of local air pollution and bear the risk to more graphitized soot. The surface of the more defected particles cause health damage. On the other hand, soot at altitude has an may have, for instance, a higher ability to attract or repulse water effect mainly on tropospheric chemistry and global warming. The favoring or not the formation of contrails but this effect is related to generation of aircraft soot with high reactivity at and close to soot present at altitude and is beyond the goal of the present paper. ground level can be considered as having both benets and disadvantages : the benecial part is related to the stage of soot for- 5. Conclusions mation in the engine where it can still react with oxygen and be partly or totallyeliminated, i.e. before reaching the exhaust. As soon Based on both the physical and chemical characterization of as it reaches the ambient air and can be inhaled, highly reactive aircraft soot, the following conclusions can be drawn from this soot can prove more harmful than less reactive one, as it has a study. higher capacity to react with its surrounding, also with cells. The results of the present study indicate that the soot type with the 1. The soot type that shows the highest reactivity is the one prohighest reactivity and thus the most prone to react with oxygen and duced with Jet A-1 fuel at ground idle conditions. Assuming that probably also when it comes into contact with cells is the one reactivity is related to the presence of atoms on the particle generated at ground idle conditions with the Jet-A-1 fuel, due to the surface and bulk available for reaction, this soot type has the small particle size and defected nanostructure. This nding is of potential to react most with oxygen and be eliminated during high signicance for the people working at airports and/or living in and immediately after its generation. It is also the soot type that the surrounding areas as these conditions at airports are prevalent. would be most prone to react with the atmospheric environ- The HEFA blend ground idle (small size), as well as the P85 soot ment and probably also with cells, when inhaled. (amorphous shell) can be also considered as highly reactive. 2. At ground idle conditions, blending of HEFA with Jet A-1 fuel Whether the particle size or the presence of the amorphous shell is decreases slightly the reactivity of the generated soot. Thus, as the more decisive parameter for rendering soot more reactive far as health risks are concerned, mixing of Jet A-1 with HEFA cannot be evaluated at this stage of research. Thus it cannot be could possibly prove benecial at airport areas where ground predicted, based on soot morphology, which soot type shows idle conditions are prevalent. higher reactivity. It is also not known how soot chemistry in- 3. At climb-out conditions the HEFA blend soot shows higher uences cell dysfunction and damage. Despite these shortcomings, reactivity thus potentially bearing higher health risk compared ample work has shown that soot can generate reactive oxygen to Jet A-1 produced soot at this thrust level. However, HEFA species (ROS) in lung epithelial cells (Garza et al., 2008) which is blending produces lower soot amounts than Jet A-1 and this known to cause adverse health effects in humans (Fuzzi et al., needs to be taken into account besides soot reactivity, in order to 2015). To our knowledge, any link between an amorphous rim on obtain the net effect. primary soot particles and generation of ROS species has not been 4. The reactivity of soot decreases with increasing engine thrust investigated in previous literature. The lack of crystallinity may level (from ground idle to climb-out conditions). HEFA blending allow for greater reaction pathways and generation of more ROS may result in a more moderate reactivity decrease at climb-out exacerbating any health impacts of soot exposure beyond what is conditions, as inferred from the presence of a reactive outermost already expected. Interestingly, a study on health effects of aircraft shell in nearly one third of the investigated soot particles. exhaust carried out within the framework of the same research project revealed that among ground idle and P85 soot with Jet A-1 Acknowledgements and HEFA blend, ground idle soot with Jet A-1 is the one with the highest impact on bronchial cells (Jonsdottir et al. Nature Comm. This research beneted from the nancial support and expertise Biology; in revision). These results are in line with the detailed soot of the Swiss Federal Ofce of Civil Aviation (FOCA, project SFLV morphology results obtained here, as the idle Jet A-1 soot was 2015-113). We greatly appreciate the continuous support of Frithjof shown to possess a combination of morphological characteristics Siegerist and Mike Weiner and his team at SR Technics Company indicating very high reactivity. One should, however, consider that during engine operation and test facility access at Zurich airport. Y. HEFA blend produces lower amounts of soot as compared to con- Arroyo Rojas Dasilva, Electron Microscopy Center, Empa Dbendorf, ventional, Jet A-1 kerosene (both particle number and mass; is acknowledged for her assistance with TEM imaging. PAA and MA Table S1 in Supplementary Information). The net effect among the appreciate funding by the Swiss National Science Foundation (grant roles of soot reactivity versus soot amount with respect to potential no 163074) and the European Union's Horizon 2020 research and health risk needs still to be evaluated and should be taken into innovation program under the Marie Skodowska-Curie grant consideration in order to assess the benet of biofuels. agreement (no 701647) and thank B. Watts for supporting the A. Liati et al. / Environmental Pollution 247 (2019) 658e667 667 operation of our experimental infrastructure at the PolLux beam- Llamas, A., Lapuerta, M., Al-Lal, A.-M., Canoira, L., 2013. Oxygen extended sooting line. The PolLux end station was nanced by the German Ministry index of FAME blends with aviation kerosene. Energy Fuels 27 (11), 6815e6822. Lobo, P., Rye, L., Williams, P.I., Christie, S., Uryga-Bugajska, I., Wilson, C.W., et al., fr Bildung und Forschung (BMBF) through contracts 05KS4WE1/6 2012. 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Combust. Flame 159 (2), 844e853. Flame 161 (2), 602e611. J. Leahy, Airbus Global Market Forecast, 2017-2036. Westbrook, C.K., Pitz, W.J., Curran, H.J., 2006. Chemical kinetic modeling study of Liati, A., Spiteri, A., Dimopoulos Eggenschwiler, P., Vogel-Schauble, N., 2012. the effects of oxygenated hydrocarbons on soot emissions from diesel engines. Microscopic investigation of soot and ash particulate matter derived from J. Phys. Chem. 110 (21), 6912e6922. biofuel and diesel: implications for the reactivity of soot. J. Nanoparticle Res. 14 Wey, C.C., Anderson, B.A., Wey, C., Miake-Lye, R.C., Whiteeld, P., Howard, R., 2007. (11), 1e18. Overview on the aircraft particle emissions experiment (APEX). J. Propul. Power Liati, A., Dimopoulos Eggenschwiler, P., Schreiber, D., Zelenay, V., Ammann, M., 2013. 23 (5), 898e905. Variations in diesel soot reactivity along the exhaust after-treatment system, Yehliu, K., Vander Wal, R.L., Boehman, A.L., 2011. Development of an HRTEM image based on the morphology and nanostructure of primary soot particles. analysis method to quantify carbon nanostructure. Combust. Flame 158 (9), Combust. Flame 160 (3), 671e681. 1837e1851. Liati, A., Brem, B.T., Durdina, L., Vogtli, M., Arroyo Rojas Dasilva, Y., Dimopoulos Yehliu, K., Vander Wal, R.L., Armas, O., Boehman, A.L., 2012. Impact of fuel formu- Eggenschwiler, P., Wang, J., 2014. Electron microscopic study of soot particulate lation on the nanostructure and reactivity of diesel soot. Combust. Flame 159 matter emissions from aircraft turbine engines. Environ. Sci. Technol. 48 (18), (12), 3597e3606. 10975e10983. From: Laureen France To: Commission-Public-Records Subject: [EXTERNAL] Public Comment -- Carbon Emissions and Accelerating Century Agenda Objectives Date: Monday, October 25, 2021 10:21:07 AM WARNING: External email. Links or attachments may be unsafe. Commissioners, Thank you for recognizing the serious impact of aviation on climate change, and proposing actions to strengthening the Port's emissions targets. I'm relieved and encouraged by your ambitious plans to reduce Scope 1 and 2 emissions, and I agree that reducing Scope 3 emissions is challenging. The Scope 3 goal for carbon neutrality is an inadequate standard, because it does not require emissions reductions. The problems with offset programs are well-documented, with few projects resulting in actual emissions reduction. Offsetting projects are largely located in the Global South and often lead to local conflicts or land grabbing. Ultimately, offsetting is a form of carbon colonialism. It enables a small share of the world population, often the wealthiest, to fly while ignoring the costs that are imposed on others. And those who bear the greatest environmental and economic costs are people whose historic contribution to climate change is negligible. For these reasons, I urge you not to use "carbon neutral" as a goal. Promotion of "Sustainable" Aviation Fuel is not a credible or acceptable policy to address aviation's climate problem; it results in slight CO2 reductions per mile flown. I am glad you recognize the limited capacity for biofuel production. "Sustainable" Aviation Fuel is simply not capable of reducing CO2 to 2007 levels by 2050, especially given the anticipated increases in flying. While you suggest that Scope 3 emissions are "outside the Port's direct control," there is something that the Port can, and should do. Instead of wishfully thinking that electric or hydrogen-powered aircraft will provide the answer, though neither option is viable for long haul trips, you could change the "Sustainable" Airport Master Plan to reflect the necessity to reduce flying. Planning for a massive increase in flying should not be a fait accompli. If the Port Commissioners believe they have no power to reduce flights into and out of our region, then perhaps they should advocate an update in the law to reflect the current massive climate crisis that may, in time, render all discussions of travel, moot. Just yesterday, the World Meteorological Organization reported that greenhouse gas concentrations hit a new record high last year and increased at a faster rate than the annual average for the last decade despite a temporary reduction during pandemic-related lockdowns. The "business as usual" approach to an unprecedented threat is disturbing. Thank you for your consideration, Laureen France From: laura gibbons To: Commission-Public-Records Subject: [EXTERNAL] Written version of the comments I just made Date: Tuesday, October 26, 2021 12:50:27 PM WARNING: External email. Links or attachments may be unsafe. Commissioners, I want to thank you for recognizing the seriousness of the impact of aviation on climate change by strengthening the Port's emissions targets. I'm impressed by your ambitious plans to reduce Scope 1 and 2 emissions, and I agree that reducing Scope 3 emissions is challenging. Promotion of "Sustainable" Aviation Fuel isn't going to get us there. It does not represent a credible policy to address aviation's climate problem, because its use results in only slight CO2 reductions per mile flown. I am glad you recognize the limited capacity for biofuel production. "Sustainable" Aviation Fuel is just not capable of reducing us to 2007 levels by 2050, especially given anticipated increases in flying. Also, the Scope 3 goal for carbon neutrality is an inadequate standard, because it doesn't require ANY reductions in aviation emissions. Problems with offset programs are well-documented, and ultimately offsetting is a form of carbon colonialism. To enable a small share of the world population to fly with a clear environmental conscience, others bear the costs: people whose historical contribution to climate change is negligible, and who are already experiencing the impacts of the climate crisis. For these reasons, I urge you not to use "carbon neutral" as a goal. You talk about Scope 3 emissions as "outside the Port's direct control", but actually there is something you can do. Instead of hoping for electric or hydrogen-powered plans, make the "Sustainable" Airport Master Plan truly sustainably by reflecting the necessary reduction in flying, rather than a massive increase. If you feel you cannot do that under RCW53, the Port must advocate for updating the law to reflect the current climate crisis. Sincerely, Laura Gibbons Seattle From: David Goebel To: Commission-Public-Records Cc: Felleman, Fred Subject: [EXTERNAL] Alaska Airlines reference to "FAA upcoming redesign of the region"s airspace" Date: Tuesday, October 26, 2021 3:42:49 PM Attachments: SeePage5-AlaskaAirSAMPComment_27Sep2018_ShaneJones.pdf WARNING: External email. Links or attachments may be unsafe. As promised today, attached is the Alaska Airlines SAMP comment I found to include in the record. See highlighted text on page 5. If this is news to you, then Alaska may know something you don't, or perhaps they're just off base. In any case worth checking out it seems to avoid being blind sighted by airspace changes like what happened with the automatic 270 degree turns on Northflow turbo-prop departures, which led to litigation with the City of Burien. Twice. Stan had to tap TRACON spies to get the bottom of that one. Thanks, David From: Commission-Public-Records Sent: Tuesday, October 26, 2021 8:28 AM To: david@vifs.org Subject: RE: [EXTERNAL] I wish to make a public comment at tomorrow's commission meeting. Thank you David Goebel, Join us via yourmobile or laptop device on through Teams or call into the number provided below at11:30 a.m. PSTon Tuesday October 26, 2021 in order to be marked present and ready to speak. A member of port staff will join the call to take a roll call of the names we have listed and go over the procedure. Please plan to call from a location with as little background noise as possible. You should expect to be on the line for between 30-60 minutes as we dispose of preliminary business on the agenda and we hear from other public commenters. While it's not possible for us to predict how many people will comment on October 26, we expect individual comment time to be limited to two minutes and all rules of order and decorum will apply as usual. If you have any questions please let us know. We appreciate your dedication to public health and your interest in participating in the Port of Seattle Commission meeting. ________________________________________________________________________________ Microsoft Teams meeting Join on your computer or mobile app Click here to join the meeting Or call in (audio only) +1 425-660-9954,,737511203# United States, Seattle (833) 209-2690,,737511203# United States (Toll-free) Phone Conference ID:737 511 203# Find a local number|Reset PIN Learn More|Meeting options ________________________________________________________________________________ Best Regards, Commission Public Records From: David Goebel Sent: Monday, October 25, 2021 11:19 PM To: Commission-Public-Records Subject: [EXTERNAL] I wish to make a public comment at tomorrow's commission meeting. WARNING: External email. Links or attachments may be unsafe. Hi, The topics will be the new GAO report on PBN implementation, the SAMP, and more if time allows. Thanks, David aska September 27, 2018 Mr. Steve Rybolt Port of Seattle Aviation Environmental and Sustainability P.O. Box 68727 Seattle, WA 98168 Re: Scope of Seattle-Tacoma Airport Sustainable Airport Master Plan proposed environmental assessment Alaska Airlines submits these comments in response to the Port of Seattle's ("the Port") request for public comment during the scoping process for the proposed actions contained in the Sustainable Airport Master Plan ("SAMP"). Alaska Airlines appreciates this opportunity to participate in the scoping phase of the Seattle-Tacoma ("Sea-Tac") Airport's proposed implementation of the SAMP. Our comments fall into three categories: how the Port should proceed with the environmental analysis of the SAMP; what that environmental review should include with respect to alternatives; and, whether some of the action items are needed so urgently they should be approved while the environmental review of the SAMP is underway. Alaska Airlines is headquartered at Sea-Tac, and the airline along with its wholly-owned subsidiary Horizon Airlines has more operations at Sea-Tac than any other carrier. Alaska Airlines is firmly rooted in this community and fully committed to the success of Sea-Tac. We are also committed to staying engaged in this process to its conclusion. As the Puget Sound region continues to expand, and projections for airline traffic continue to grow, a smoothly functioning, properly equipped, operationally efficient and environmentally sustainable Sea-Tac Airport is critical for our community, area residents, and the regional economy. aska September 27, 2018 First, Alaska Airlines asks the Port to reconsider sow these proposals should be examined in order to ensure compliance with all applicable environmental statutes. We believe the scoping phase of the SAMP is a step in the right direction in preparing Sea-Tac for the implementation of this ambitious program. At the same time, we are concerned that the Port and the Federal Aviation Administration ("FAA") may be jeopardizing the SAMP's implementation by proposing to meet the rigorous requirements of the National Environmental Policy Act ("NEPA") with an environmental assessment ("EA") rather than an environmental impact statement ("EIS"). Alaska Airlines believes this is a mistake and strongly encourages the Port to ~~ reconsider. Instead, we believe it is in the best interest of the SAMP, the community, the x environment, and all stakeholders concerned about the future of this airport for the Port to meet its legal requirements under NEPA with an EIS, rather than an EA. Anticipating the heightened scrutiny this project will likely face, we believe that the Port should take the time and effort to develop a full EIS. Making this decision now will help ensure the most rigorous standard of environmental review, and be more cost-effective and efficient over the long term. While preparing an EIS may require more upfront time and effort than if the Port were to develop an EA, Alaska Airlines believes this additional time would ultimately be an effort well spent. Preparing an EIS eliminates the need to make a finding of no significant impact (FONSI) which in a project of this magnitude could be more difficult than demonstrating procedural compliance with the EIS process. In addition, preparing an EIS could produce more substantive stakeholder feedback and fully effectuate the stated goals of the SAMP projects. As a result, an EIS may ultimately be more cost-effective than generating an EA, as any major litigation delay will almost certainly drive up the total cost of the project as construction deadlines are impacted. 2 aska September 27, 2018 What is more, if the Port decides to proceed with an EA, there may be a strong likelihood that the Port may only be able to justify a finding of no significant impact if it straps a host of massive mitigation projects to the FONSI. Such mitigation proposals could have the potential to saddle the Port and Sea-Tac operations with numerous, potentially onerous obligations that may 2h] never have been contemplated within the SAMP. These obligations may not end with approval of the proposed actions. If project opponents conclude at some point in the future that there has been a failure to continue to honor ongoing mitigation commitments, they could initiate additional litigation risk assailing the effectiveness of mitigation measures adopted in the FONSI. This uncertainty could continue years after project approval, for as long as mitigation measures remain in place. As a result, an EA/FONSI that requires extreme mitigation may well be more difficult to implement than taking the time to prepare an EIS, which would not require such mitigation proposals. Second, Alaska Airlines urges the Port to expand what the forthcoming environmental analysis should consider. At present, the range of alternatives slated for detailed consideration is inadequate. In NEPA analysis, if an alternative satisfies the project's Purpose and Need and is feasible, that alternative warrants close scrutiny in the EIS or EA. Here, the Port has stated that the Purpose and Need for the projects identified in the SAMP is to address concerns that are Ak-L applicable to the entire airport. As a result, the Port's decision to address future airport-wide demands by considering only North Terminal alternatives is both ill-advised and legally inadequate, especially when another feasible alternative is available. aska September 27, 2018 Alaska Airlines has demonstrated that an alternative involving extensions and/or modifications to existing concourses in the Main Terminal is a viable, feasible alternative that can satisfy the SAMP's Purpose and Need when paired with certain roadway and other improvements considered in the SAMP and others in the main terminal and transportation access that would be ancillary to this work. The alternative proposed by Alaska Airlines would address inefficiencies in the existing terminal, inadequacies which would be unaffected by the proposals in the SAMP. Alaska Airlines' alternative merits detailed consideration in the NEPA process. There are at least several benefits that could result if the alternative proposed by Alaska Airlines is given detailed consideration in the NEPA process. Alaska Airlines has shown that the % proposal advanced in the SAMP poses a substantial risk of overbuilding. The SAMP ignores already approved construction projects, including the North Satellite Modernization Project, the International Arrival Facility, and Concourse D Annex project. These projects will add approximately 25% more aircraft parking positions by 2022 than existed in 2017. Even with conservative utilization of these additional facilities, this added capacity will accommodate the 2027 demand forecast. Also, detailed consideration of a more modest alternative would provide the Port and stakeholders with beneficial flexibility in selecting an alternative that meets the SAMP's Purpose and Need without overbuilding. If the concerns of Alaska Airlines are validated and the Port concludes at the conclusion of the NEPA process that the actions proposed by the SAMP are not aska September 27, 2018 needed, failure to consider a more modest alternative now would require beginning the NEPA process anew, which would be an unfortunate waste of time and resources. = Additionally, and separate from the SAMP environmental assessment, the Port plans to conduct an in depth study of the most significant factor contributing to delay at the airport: the limitations on current airspace capacity. Clearly, the overall impact of significant improvement in the region's airspace can play a role in addressing airport delay. The failure to makeadequate airspace revisions could compromise the expected benefits ofthe SAMP. Therefore, it is unclear how the proposed environmental analysis could objectively evaluate the SAMP without incorporating the findings of an airspace study or why the two are not part of the same work Mv AA stream. Notably, the timing for conducting the airspace study will preclude its consideration in the SAMP environmental review. This makes no sense. substantially expanding a railroad station without addressing the need for additional train tracks. The Port should not commit to building the proposed terminal facilities for projected growth without some credible plan to make room in the sky for those additional aircraft. Respectfully, Alaska Airlines suggests that when confronted with projections of future growth at Sea-Tac, the Port and the many stakeholders should not be tempted to pursue an overly Ap ambitious response when that response is likely to impose severe operational, customer experience, and financial constraints upon the Port, air carriers, and passengers. It would be especially unfortunate if the burdens of implementing these audacious projects had the effect of Alaska September 27, 2018 precluding needed improvements to the Main Terminal where 80% of the airport's passengers will continue to transit, even with a fully-operational new North Terminal. Indeed, using the x Port's own data from Leigh Fisher on forecast delay, it is possible that implementation of the < SAMP actions could adversely affect the airport's ability to compete with other airports in attracting new carriers and new service. R_ Finally, Alaska Airlines requests that the Port examine whether some of the proposed actions in the SAMP could be implemented in the immediate future rather than waiting for the completion of the NEPA analysis. The FAA has adopted procedures in FAA Order 1050.1F that allow for documented categorical exclusions.! Alaska Airlines believes that certain proposed + actions, such as the high-speed taxiway for Runway 34L as identified as an airport improvement 5 in the SAMP, has independent utility and could be reviewed through the mechanism of a documented categorical exclusion. Importantly, swift approval of these measures could provide important environmental, customer, and operation benefits, and may not need to be subject to detailed environmental scrutiny. Thank you for your consideration ofthese comments. Sincerely, Shane Jones Vice President Airport Real Estate and Development "FAA, Order 1050.1F, at 1-6 (July 16, 2015), https://www.faa.gov/documentLibrary/media/Order/FAA_Order10501F.pdf. From: Anne Kroeker To: Commission-Public-Records Cc: Richard Leeds Subject: [EXTERNAL] Written Public Comments for 10/26/21 Commission Meeting Date: Tuesday, October 26, 2021 8:54:55 AM WARNING: External email. Links or attachments may be unsafe. Dear Port of Seattle Commissioners and Staff, Thank you for addressing the dire need to reduce carbon emissions from all port-related activities. Please consider identifying only quantifiable standards, away from ideologic ones, such as the ones you have outlined as carbon neutral or net zero, as you determine the Port's GHG emissions goals. The methods to achieve these goals either include offsets, which is an inequitable way to allow the privileged to continue to produce emissions, or are energyintensive and haven't been proven to pencil out. In both cases, other noxious emissions are continued to be produced at the tailpipe. As you present, Scope 3 emissions are outside the Port's direct control, but they are within the Port's indirect control. It is the latter category which must be emphasized as critically important to attack more vigorously, if our society is to make any progress in reducing our growing carbon emissions. It is the direct aircraft usage by the public which allow emissions to be produced and if the Port were to shutdown, so would these emissions coming to and from this airport. This is an extreme example but it does illustrate the power that the Port does hold. To date, no Commissioners nor Port staff have been willing to look at the potential of reducing the "need" to fly, which is why all reduction goals continue to be unattainable. Promotion of biofuel production for jet fuel replacement is a good idea in that it does lower the carbon emissions production cycle, if implemented properly, but it does not represent a credible or acceptable policy to address aviation's climate problem, as the reductions are slight and inconsequential next to aviation growth. In addition, asking all taxpayers to pay for the development of alternative aviation fuels is inequitable when only a small percent of the population reap the benefits. The argument that aviation is good for our whole economic balance is still trickle-down theory, which has been disproven time and again. Thank you for accepting the above comments and I hope that you may consider them in your review as you create stronger GHG emissions goals, for all of the Port's sanctioned activities. Sincerely, Anne Kroeker and Richard Leeds Scope 1 & 2 emissions(these are emissions generated by direct operations, or by electricity generation that buildings use) Current goals: o 50% below 2005 levels by 2030 o Carbon neutral by 2050 New scope 1 & 2 goals: o Net zero by 2040 Scope 3 emissions: (these include emissions from planes and ships; these dwarf the others in magnitude) Current goals: o 50% below 2007 levels by 2030 o 80% below 2007 levels by 2050 New scope 3 goals: o 50% below 2007 by 2030 o Carbon neutral by 2050 From: Laura Loe To: Commission-Public-Records Subject: [EXTERNAL] Cruise Ships - Laura Loe 10/26 Date: Monday, October 25, 2021 11:45:17 PM WARNING: External email. Links or attachments may be unsafe. I'd like to provide public comment for the 10/26 meeting. - Please halt all expansion of fossil fuel infrastructure, especially related to cruise ships. Cruise ships are not good for air, water, climate change, or labor rights. I'm a renter in 98119 and lead a nonprofit called Share The Cities Action Fund and I am very worried about the Port doing more to fight climate change and take a lead on this issue. Please educate members of the public about the health and climate impacts of all decisions that you are making, not just short term economic perceived benefits. The long term harm to our economy from global warming is far more serious than losing money from fewer or no cruise ships. Thanks for supporting other advocates also pushing for safer communities in the Duwamish and SeaTac. Listen to the environmental justice demands of local communities we elected you to help protect us from global systems focused on profit over people's health. -- Laura Loe She/Her Executive Director, Share The Cities Action Fund From: Bernedine Lund To: Commission-Public-Records Subject: [EXTERNAL] Tuesday Oct 26 POS COmmissioner public comments Date: Monday, October 25, 2021 10:02:25 PM Attachments: public comments 10-26-21.pdf WARNING: External email. Links or attachments may be unsafe. Hi, attached is a file with my public comments for item 10c on the agenda - Carbon emissions etc. I will try to be on the call by phone to give the public comment in person. I may be under the kitchen sink mopping up and fixing a water leak, and could take a break to give the public comment. In this case I would rather be doing the public comment than laying on my back under the sink - maybe the store won't have a faucet we need! Have a good week. Bernedine Lund 253-829-3729 Public Comment, PoS Commissioner's meeting 10-26-2021, Agenda Item 10c Carbon Emissions and Accelerating Century Agenda Objectives; Bernedine Lund, resident of Federal Way and volunteer for 350 Seattle Aviation Group Hello, Commissioners, Thank you for allowing me to comment on your plans for resetting the PoS's emissions goals. I was very happy to see that the proposal is to reduce emissions to 0 by 2040, 10 years early. My other comments are on the presentation for Agenda item 10c - Carbon Emissions and Accelerate Century Agenda Objectives, slide 14. Slide 14 shows that for Scope 3, the Port proposes to reach the goal of 0 emissions by 2040 using the two strategies 1) Net-Zero strategy and 2) Carbon neutral/negative strategy as needed, while at the same time increasing the number of flights. Both strategies have serious negative issues and may not give the results of reducing CO2 you expect. The Net-zero strategy proposal is to remove CO2 from air; however the process currently is highly energy intensive, has not been tried in large scale efforts, and does not address other emissions. The carbon neutral/negative strategy uses offsets and has been highly criticized because it moves the responsibility of carbon reduction to other entities, such as third world countries, and is most likely to create other problems along with no CO2 reductions. It seems unconsciousable (unwise, ill-advised, etc.) for the PoS to still plan an expansion as outlined in the SAMP. By planning to greatly increase the number of flights means you also need to greatly decrease aircraft emissions using strategies you hope work. Not to reduce the emissions means you will not meet the Scope 3 goals, one of which is to make flying equitable to both flyers and non-flyers. The proposal also still includes using biofuels. You must be aware of the increasing number of concern s about using biofuels and the negative impact it is having on poorer countries. It also seems unwise to rely on a strategy that has yet to be proven at scale. Not expanding flights is still the best known way to meet the emissions goals. This is the only way that it will be equitable for both flyers and non-flyers. This strategy is being pursued in places that are saying "No" to airport expansions due to pressure from local residents. Not expanding also gives time to airline and other industries to develop technologies that will not produce emissions. From: Rosemary Moore To: Commission-Public-Records Subject: [EXTERNAL] AMENDED Written Comment for Port Commission meeting 10/26/21 Topic: Revised Emission Goals Date: Monday, October 25, 2021 3:18:30 PM WARNING: External email. Links or attachments may be unsafe. UPDATED Comments: Commissioners, Thank you for recognizing the seriousness of the impact of aviation on climate change by strengthening the Port's emissions targets, in particular to reduce Scope 1 and 2 emissions. While I agree that reducing Scope 3 emissions is challenging I believe that the Port Commission's proposed Scope 3 goals are inadequate and far too passive. Until or unless there is an actual and realizable method of zero/very low-emission flying, the Port must require and work for a reduction in flying. If you feel that a change in the law is necessary to accomplish this, then you must advocate to update the law accordingly. The Port Commission also has contracting powers that can be used to impose adequate standards on third parties. The Scope 3 goal for carbon neutrality is an inadequate standard, because it doesn't require ANY reductions in emissions. I urge you not to use "carbon neutral" as a goal. Problems with offset programs are well-documented, with few projects resulting in additional emissions reduction. To enable a small share of the world population to fly with a clear environmental conscience, others bear the costs. Your goal of achieving "Net-zero" by removing CO2 from the air is highly energy intensive, has not been tried or shown to work in large scale efforts, and does not address other emissions. Promotion of "Sustainable" Aviation Fuel, hydrogen, biofuel, electric planes do not at present represent a credible or acceptable policy to address aviation's climate problem, because they result in only slight CO2 reductions per mile flown, if any. I am glad you recognize the limited capacity for biofuel production. "Sustainable" Aviation Fuel is just not capable of reducing us to 2007 levels by 2050, especially given anticipated increases in flying. As our commissioners you cannot merely cross your fingers and hope there will be a technological solution, be it hydrogen, electric or something else. As our commissioners, you need to make firm decisions based on what we know and can be certain of now. We face a crisis it cannot simply be business as usual. I urge you to change the "Sustainable" Airport Master Plan to reflect the necessary reduction in flying, not a massive increase. Thank you, Rosemary Moore 6230 East Mercer Way Mercer Island WA 98040 Cell: (1) 206 251 7009 From: Rosemary Moore Sent: Monday, October 25, 2021 2:53 PM To: commission-public-records@portseattle.org Subject: Written Comment for Port Commission meeting 10/26/21 Topic: Revised Emission Goals Commissioners, Thank you for recognizing the seriousness of the impact of aviation on climate change by strengthening the Port's emissions targets, in particular to reduce Scope 1 and 2 emissions. While I agree that reducing Scope 3 emissions is challenging I believe that the Port Commission's proposed Scope 3 goals are inadequate and far too passive. Until or unless there is an actual and realizable method of zero/very low-emission flying, the Port must require and work for a reduction in flying. If you feel that a change in the law is necessary to accomplish this, then you must advocate to update the law accordingly. The Port Commission also has contracting powers that can be used to impose adequate stricter standards on third parties. The Scope 3 goal for carbon neutrality is an inadequate standard, because it doesn't require ANY reductions in emissions. I urge you not to use "carbon neutral" as a goal. Problems with offset programs are well-documented, with few projects resulting in additional emissions reduction. To enable a small share of the world population to fly with a clear environmental conscience, others bear the costs. Promotion of "Sustainable" Aviation Fuel, hydrogen, biofuel, electric planes do not at present represent a credible or acceptable policy to address aviation's climate problem, because they result in only slight CO2 reductions per mile flown, if any. I am glad you recognize the limited capacity for biofuel production. "Sustainable" Aviation Fuel is just not capable of reducing us to 2007 levels by 2050, especially given anticipated increases in flying. As our commissioners you cannot merely cross your fingers and hope there will be a technological solution, be it hydrogen, electric or something else. As our commissioners, you need to make firm decisions based on what we know and can be certain of now. We face a crisis it cannot simply be business as usual. I urge you to change the "Sustainable" Airport Master Plan to reflect the necessary reduction in flying, not a massive increase. Thank you, Rosemary Moore 6230 East Mercer Way Mercer Island WA 98040 Cell: (1) 206 251 7009 From: Eric Ross To: Commission-Public-Records Subject: [EXTERNAL] Requested Link to Study on Public Health Impacts from Port activities Date: Tuesday, October 26, 2021 3:12:13 PM WARNING: External email. Links or attachments may be unsafe. Dear Port of Seattle, Thank you for listening to the concerns of community members and reflecting those concerns in the accelerated timeline towards zero emissions in the Maritime Clean Air Action Plan. Here is the study I (Eric Ross) and commissioner Fred Felleman referenced concerning health impacts of air pollution from port operations and the shipping sector. Commissioner Fred Fellerman askedif there was a study that linked impacts of air pollution on public health to operations at ports. This study by the International Council on Clean Transportation does just that. The study found that "the areas of Seattle and San Francisco lead in terms of early deaths per 100,000 residents (1.8 and 1.6), or more than double the global average, due to air pollution from the ports of Seattle, Tacoma, Oakland, and San Francisco." Link to Study:https://theicct.org/sites/default/files/publications/Global_health_impacts_transport_emissions_2010- 2015_20190226.pdf On the ICCT websitethey summarized some of methodologies and metrics, and findings: Agroup of researchers from the ICCT, The George Washington University Milken Institute School of Public Health, and the University of Colorado Boulder released a new study assessing premature mortality associated with air pollution from transportation. The study found that fine particulate matter (PM2.5) and ozone from on-road vehicles, non-road engines, and oceangoing vessels was linked to an estimated 385,000* premature deaths in 2015 worldwide. About half of these deaths were attributed to air pollution from diesel cars, trucks and buses. But a surprisingly large fraction of the early mortality approximately 15%, or 60,000 deathswere due to air pollution from the 70,000 international ships that ply the world's oceans. That equates to about 160 billion dollars of health damages annually. The study assessed health impacts using methods from the Global Burden of Disease (GBD) 2017. The methodology used can be considered conservative* in the number of deaths estimated. As a result, the estimates of air pollution health impacts are lower than other studies, and could be revised upward if any of these assumptions are relaxed. Still, the study highlights the uneven distribution of premature mortality due to air pollution from international shipping. It provides the raw data, which allows anyone to run their own secondary analysis. We put together a follow-up analysis of shipping impacts using that data, and found some interesting results, namely that many of these deaths occur in places one might not expect. Despite recent adoption of more stringent vehicle emission regulations in some major vehicle markets, the transportation sector remains a major contributor to the air pollution disease burden globally. This points to the need for reducing emissions from the transportation sector to be a central element of national and local management plans aimed at reducing ambient air pollution and its burden on public health. Longer term, eventually we'll need completely carbon-free ships powered by electricity, hydrogen... Thank you for your work, -Eric Ross 860-605-0776 From: Jordan Van Voast To: Commission-Public-Records Subject: Re: [EXTERNAL] public comment Date: Tuesday, October 26, 2021 7:33:57 AM Attachments: 10.26.21.emailed to council version.docx Thank you. Please share a slightly longer version of my oral comments with the Commission (attached). On Mon, Oct 25, 2021 at 8:57 AM Commission-Public-Records wrote: Thank you Jordan Van Voast, Join us via yourmobile or laptop device on through Teams or call into the number provided below at11:30 a.m. PSTon Tuesday October 26, 2021 in order to be marked present and ready to speak. A member of port staff will join the call to take a roll call of the names we have listed and go over the procedure. Please plan to call from a location with as little background noise as possible. You should expect to be on the line for between 30-60 minutes as we dispose of preliminary business on the agenda and we hear from other public commenters. While it's not possible for us to predict how many people will comment on October 26, we expect individual comment time to be limited to two minutes and all rules of order and decorum will apply as usual. If you have any questions please let us know. We appreciate your dedication to public health and your interest in participating in the Port of Seattle Commission meeting. __________________________________________________________________________ ______ Microsoft Teams meeting Join on your computer or mobile app Click here to join the meeting Or call in (audio only) +1 425-660-9954,,737511203# United States, Seattle (833) 209-2690,,737511203# United States (Toll-free) Phone Conference ID: 737 511 203# Find a local number | Reset PIN Learn More | Meeting options Good afternoon Port Commissioners and Director Metruck, my name is Jordan Van Voast. I am here to speak about the Port of Seattle's new climate goals. In short, these goals woefully fail to address the scope of the climate emergency. Whether it's achieving "Net Zero on Scope 1 and 2 by 2040" or , "Carbon Neutral" on Scope 3 by 2050, these targets out 20 and 30 years are not going to prevent emissions from continuing to rise now and that's what we need a plan for. With every bunker fuel burning cruise ship pulling away from Seattle's harbor and the hundreds of thousands of air travelers who come here to board a cruise, any hope of limiting global warming to 1.5 degrees above preindustrial baseline slips further over the horizon. The lives of millions of people and billions of animals and marine species are on the line. And it gets exponentially worse every moment we delay with false solutions1. Days ago, hundreds died in India and Nepal due to record breaking late monsoon rains and flooding. Does anyone even remember the heat dome of 2021?2 Yesterday's "bomb cyclone" making it's way across the U.S. to the East Coast was reportedly the largest storm ever to hit the west coast with severe flooding, mudslides, and loss of life. What next? While net zero is still a better goal than carbon neutral, both are rooted in a deep denial of the severity of the crisis we are in and the apocalyptic future that our children may face. To avert this crisis, we need to confront our denial, reign in our magical thinking and reduce all non-essential emissions now, not setting targets for 30 years away that depend upon technologies that aren't available. Cruising is a nonessential business with a gigantic emissions and ecological footprint and it needs to end. Thank you. 1 https://stevemaclellan.com/two-fatal-flaws-with-net-zero-by-2050-net-zero-and-by-2050/ 2 https://www.theguardian.com/environment/2021/jul/08/heat-dome-canada-pacific-northwest-animal-deaths Global greenhouse gas emissions and warming scenarios SUSE in Data - Each pathway comes with uncertainty, marked by the shading from low to high emissions under each scenario. - Warming refers to the expected global temperature rise by 2100, relative to pre-industrial temperatures. Annual global greenhouse gas emissions in gigatonnes of carbon dioxide-equivalents 150 Gt No climate policies 4.1-48C >expected emissions in a baseline scenario if countries had not implemented climate reduction policies. 100 Gt 50Gt ewe maa, Current policies 2.7-3.1C -" emissions with current climate policies in place result in warming of 2.7 to 3.1C by 2100. Greenhouse gas emissions up to the present Pledges & targets (2.4 C) emissionsifall countries delivered on reduction pledges result in warming of 2.4C by 2100. 2C pathways 1.5C pathways 1990 2000 2010 2020 2030 2040 2050 2060 2070 2080 2090 2100 Data source: Climate Action Tracker (based on national policies and pledges as of May 2021). Last updated: July 2021. OurWorldinData.org - Research and data to make progress against the world's largest problems. Licensed under CC-BYby the authors Hannah Ritchie & Max Roser.
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